Polar Molecule Definition

A polar molecule is a chemical species in which the distribution of electrons between the covalently bonded atoms is not even. Polarity is a description of how different the electrical poles of a molecule are. If they are highly different, it can be said that the species is a highly polar molecule. Some chemical species, such as chains of carbon molecules, share electrons equally and are said to be nonpolar molecules. Typically, the designation of whether a molecule is polar or nonpolar comes from the sum of all of its bonds considered together. Each atom has a certain electronegativity. When bonded to another atom, the atom with the higher electronegativity will tend to attract more electrons. If the difference is not great, a nonpolar bond is formed. If the difference is considerable, a polar bond will form and one atom will attract more electrons. In the more extreme cases, the atom with the greater electronegativity will strip the electrons from the first atom and not share them at all. This creates an ionic bond which is simply an attraction between the two species of atom which are positive and negative. Because they do not share electrons, no physical bond connects these species, and they are considered ions in a matrix and not polar molecules.

Examples of Polar Molecule


The most important polar molecule on Earth is water. As seen in the image below, water is a polar molecule due to the strong electronegativity of the oxygen atom. This forces most of the electrons to the side of the molecule where oxygen is present, creating a highly negative area. The other side of the molecule becomes more positive, due to the protons of the hydrogen atoms. The polarity of this molecule can create a huge number of reactions in the environment. It can dissolve ions and other polar molecules, and can create temporary hydrogen bonds with other water molecules. Because water is a polar molecule which can interact with other water molecules, it creates a more stable structure. This enables water to have a high heat capacity, or ability to store the energy of heat in these bonds. While it takes a lot of energy to heat water up, it also stays warm for a longer time than most liquids. This is part of the reason life is possible on Earth, because water can carry heat to regions of the plane that receive little sun energy.

Water is polar molecule


Another simple polar molecule is ammonia. The chemical formula of ammonia is NH3 and it can be seen structurally in the image below. The nitrogen atom, like the oxygen in water, is much more electronegative than the attached hydrogens. This causes an uneven distribution of electrons and makes ammonia a polar molecule. Ammonia, while used as cleaner, is found in nature as a waste product. Fish and other aquatic animals dispel ammonia directly, while terrestrial animal often convert it to urea and other, less-toxic forms. Because ammonia is a polar molecule, it can be dissolved by water. As ammonia is a by-product of the breakdown and creation of proteins and bodily substances, most excretory systems rely on water to flush ammonia from the body.


  • Polarity – The measure of electrical difference within a molecule, bond, or structure.
  • Nonpolar Molecule – A molecules make of electronegatively similar atoms, which distributes electrons equally.
  • Amphiphilic Molecule – Some large molecules which have both polar and nonpolar regions, such as the phospholipids used to create cell membranes.
  • Electronegativity – The measure of the attraction an atom has for electrons, which can determine the polarity of bonds formed with that atom.


1. When sodium (Na) and chlorine (Cl) combine, the highly electronegative chlorine steals all the electrons from sodium. The two then exist in a matrix, the highly positive Na+ ions being attracted to the negative Cl ions. Which type of molecule is this?
A. Polar Molecule
B. Nonpolar Molecule
C. Not a molecule

Answer to Question #1
C is correct. This is not a molecule. A molecule requires covalent bonds to be formed, which share electrons between atoms. These ions, which do exist in a tight matrix because of their attraction to each other, can easily be separated by a polar solvent such as water. A molecule, on the other hand, might be distributed by a solvent, but has much stronger bonds between atoms created by the sharing of electrons.

2. The following elements have the corresponding electronegativity:
Oxygen: 3.44
Chlorine: 3.16
Hydrogen: 2.2

Which of the following substances is the MOST polar molecule?

A. HCl
B. H2O
C. O2

Answer to Question #2
B is correct. Water is the most polar molecule because a bond between oxygen and hydrogen has the most difference out of the atoms listed. Although the oxygen has two hydrogens bonded, this does not decrease the electronegativity of oxygen, but oxygen unfairly shares sets of electrons from both hydrogens, making it more polar still. The bond of HCl is also polar, just not as much as water. Oxygen as a molecule, or O2, is not a polar molecule because the electronegativities are equal. However, because the electronegativities are so high, dioxygen can form hydrogen bonds with water molecules, allowing it to be transported throughout the body.

3. As discussed in the article, ammonia is a polar molecule produced as a waste product. Why do fish continue to produce ammonia, while terrestrial organisms have switched to less toxic forms of waste?
A. Fish are less evolved than terrestrial organisms.
B. Terrestrial organisms needed a nonpolar molecule.
C. Terrestrial organisms have a need to conserve water.

Answer to Question #3
C is correct. To say any animal is more evolve than other is silly, because all organisms alive today have been evolving for the same amount of time, and many share common ancestors. The reason fish never evolved to concentrate their ammonia was because they have an unlimited supply of water. Terrestrial organisms, on the other hand, have a limited supply of water and cannot be flushing ammonia from the body constantly with it. Instead, the ammonia is concentrated into another polar molecule, but one which is much larger. In this way, less water is used to expel each molecule of waste, and water is conserved.